HYDROGEN POWER:
Bringing Fuel Cells Down to Earth
Robert F. Service
Automakers are banking on fuel cells, used to run equipment aboard spacecraft, to
power the first zero-emission vehicles; the type of fuel that supplies the cells could
determine how deeply these cars penetrate the market
Hydrogen has long been touted as the fuel of the future. Combine it with oxygen in a
fuel cell, and it will give you electricity and a little heat, with one byproduct: water.
Trouble is, the future never quite seems to arrive. Although fuel cells helped the Apollo
astronauts make it to the moon, they have never made much of an impact on Earth. But if
you listen to automakers these days, you may think they've seen the future--and that the
future is on its way to a showroom near you.
In a bid to keep up with ever tighter air pollution standards, automakers are pushing
hard to introduce fuel cells to mundane family sedans and pickup trucks. Virtually every
major car company is now working on the technology. Early demonstration vehicles running
on hydrogen and methanol are already on the road. The California Fuel Cell Partnership, a
new collaboration between car- and fuel cell-makers, oil companies, and government
agencies, plans to put some 50 demo cars and buses through their paces in the next 4
years. And DaimlerChrysler is so confident the partnership will like one of the early
designs that it has promised to roll out 40,000 fuel cell vehicles by 2004. If fuel cells,
as expected, become cheaper and can match the performance of traditional car engines, they
"will be the most prominent power source in the next century," predicts Ron Sims
of Ford's research lab in Dearborn, Michigan.
Those are brave words, considering that the internal combustion engine--thanks to a
stream of technological advances since Henry Ford's day--has managed to beat back
challenges from every upstart alternative for powering automobiles. And the fuel cell's
challenge could be blunted by a bruising battle over which fuel should provide the
hydrogen the cells will consume. It's a battle that could undermine the technology before
it ever gets up to speed.
Engineers and clean-air experts say the simplest and cleanest option is hydrogen gas
itself. But it would cost tens of billions of dollars to outfit all the filling stations
in the United States to supply hydrogen--not to mention an intense marketing campaign to
convince the public of the safety of a fuel still associated with the fiery demise of the
Hindenburg, a hydrogen-filled zeppelin, in 1937. Car and oil companies would prefer to
equip vehicles with miniature chemical factories to convert liquid fuels, such as gasoline
or methanol, into hydrogen gas that can be fed into fuel cells. Critics, meanwhile, argue
that the converters likely will be expensive and prone to breaking down. "Everybody
is pushing their own version of the technology," says Reinhold Wurster, a fuel cell
expert at LB Sustain Technique in Ottobunn, Germany.
The outcome of this battle will set the course for fuel cell technology--and perhaps
alter the world's energy map--well into the next century. Because the United States uses
over 40% of the gasoline produced globally, "it's the gorilla that drives the rest of
the world," says John Turner, a fuel cell expert at the U.S. Department of Energy's
(DOE's) National Renewable Energy Lab in Golden, Colorado. "What we do here will have
a lot of influence on future energy use."
Space-to-Earth odyssey. Fuel cells didn't start nipping at the heels
of traditional car engines overnight. The technique was invented in 1839--more than 20
years before the first internal combustion engine--by Sir William Grove, a Welsh judge who
began his career as a physicist. He shot an electric current through water, splitting the
molecules into oxygen and hydrogen. When the gases recombined in his experimental cell,
Grove noted, they produced a current.
The technology remained little more than a curiosity until the late 1950s, when General
Electric developed proton-exchange membrane (PEM) fuel cells as a lightweight solution for
providing onboard electricity to the Gemini spacecraft that put some of the first U.S.
astronauts in orbit. Around that time, other firms developed alkaline fuel cells, which
use a liquid electrolyte instead of a membrane to control the flow of charged ions in the
cell. Alkaline cells proved more efficient for cosmic voyages: Space shuttles still use
them to generate about 45 kilowatts (kW) of power. But this electricity comes at a pretty
penny. The shuttle's alkaline cells typically cost more than $500,000 per kW, about 10,000
times the price--roughly $50 per kW--that would start to interest carmakers.
To avoid fuel cell sticker shock, firms are revisiting GE's PEM technology as a rough
blueprint for making fuel cells for cars. Since first starting to tinker with this design
in the mid-1980s, Ballard Power Systems of Burnaby, Canada, for one, has developed fuel
cell assemblies that generate 25 kilowatts of power (a trio of which can power a family
sedan) and run at a cool 85 degrees Celsius. Along the way Ballard has lowered the price
100-fold, to about $275 per kilowatt. Based on this success, and the belief that the price
will be right when fuel cells are made en masse, Ballard has inked investment and research
deals with major automakers totaling more than $1 billion.
Ballard projects that, by converting hydrogen to electricity directly, fuel cell
engines could make productive use of up to 60% of the power generated; internal combustion
engines, by comparison, squander about 75% of the power they generate. That should allow
hydrogen vehicles to travel about 87 miles per gallon (37 kilometers per liter), without
the tailpipe pollutants of today's cars. What's more, according to Wurster, fuel cell
engines --thanks to a simpler design--should be cheaper than combustion engines when
mass-produced. Such attributes, says Sims, make fuel cell vehicles the leading contender
to meet California's strict clean air rules, which require that 10% of cars sold in the
state after 2003 produce zero emissions. Maine, Massachusetts, New York, and Vermont are
all mulling over similar zero-emissions laws, too.
Nagging questions. Despite the impressive achievements at Ballard and
other fuel cell-makers, many observers say the technology has a bumpy road ahead. Looming
over the industry is the question of which fuel will power tomorrow's cells--a "major
topic that will drive fuel cells for the next 5 years," says Neil Rossmeissl, who
manages the hydrogen research program at DOE in Washington, D.C.
Gasoline is the obvious default option, as the infrastructure for delivering it to cars
is already in place. But gasoline has a big strike against it: It is composed of a broad
mix of hydrocarbons that must be converted--or in industry parlance,
"reformed"--to hydrogen. That makes the onboard conversion plant, or reformer,
very difficult to design and has put gasoline reformer technology "at least a decade
behind" reformers that work with methanol, a simpler hydrocarbon, says C. E.
"Sandy" Thomas, who analyzes fuel cell economics at Directed Technologies Inc.
in Arlington, Virginia. Oil companies would also have to create a new grade of gasoline
purged of impurities that can ruin reformer catalysts.
With gasoline thus trammeled, methanol has sprinted ahead. Although only half as
energy-dense as gasoline--cars would need nearly a double-sized fuel tank for a similar
cruising range--methanol is a liquid at room temperature, which means that it can be
handled and transported more easily than gaseous hydrogen. According to a recent analysis
by Thomas and others, U.S. chemical companies now have the capacity to produce enough
methanol to support 1.5 million fuel cell vehicles. A study financed by the American
Methanol Institute in Washington, D.C., concluded last year that each gas station that
wants to sell the highly corrosive fuel would have to install a new type of underground
tank that costs about $50,000. Vehicles too would have to be equipped with special tanks.
Still, Daimler-Chrysler, Honda, and others say they are betting on methanol. "For the
everyday conventional car, methanol seems to be the fuel of choice," says Wurster.
A second look. But others argue that the economics, environmental
concerns, and science favor a dramatic shift in car fuels to hydrogen gas. "As you go
from direct hydrogen to methanol to gasoline, you increase the levels of emissions,"
explains Sims. "Many people think hydrogen is a dark horse," adds Thomas.
"But if you look at all the different costs, it comes out ahead."
Perhaps the biggest impediment facing hydrogen-powered vehicles is building from
scratch an infrastructure for distributing the gas. Today, U.S. chemical plants make
hydrogen gas and ship it nationwide by chilling it to 20 degrees above absolute zero, at
which point it becomes a liquid. Because that takes a lot of energy, Thomas argues that it
would be better for each filling station to make its own hydrogen and store the gas in
underground tanks. Gas stations could run electrolysis machines at night, when electricity
is cheaper, turning water into hydrogen and oxygen. Or existing natural gas pipelines
could deliver hydrocarbons such as methane, which can be reformed easily to hydrogen.
Either scheme would cost less than $1 to create an amount of hydrogen equivalent to a
gallon of gasoline, Thomas contends.
Big savings would also come from doing away with the need for reformers in cars.
"The typical automobile is used less than 2 hours a day," and even then its
engine is rarely working at full capacity, says Thomas. "If I take the onboard
reformer from one fuel cell vehicle and put it on the curb, it could serve 110
vehicles" by churning out hydrogen continuously, he says. With all the costs factored
in, Thomas calculates that creating the infrastructure to power fuel cells with methanol
would cost roughly $1300 to $2800 per vehicle. Gasoline comes in at around $2350 to $5200,
largely due to a more complex reformer. And hydrogen would add about $990 to $1150. The
extra expense for reformer-based systems, along with the likelihood of the complex devices
breaking down, says Turner, could sour consumers on fuel cell cars early on. "If that
happens, everybody loses," he says.
Critics, however, contend that hydrogen is impractical for long hauls. Because of the
gas's low density, even a pressurized steel tank would have to be about four times the
size of a conventional one to give a hydrogen-powered car the same 560-kilometer range as
a 1999 Ford Taurus, says Sims. Rossmeissl and others note that experimental lightweight
carbon-fiber tanks and other improvements could extend the driving range of
hydrogen-powered cars.
The dominant fuel should emerge in the next few years, say Sims and others. Hydrogen is
poised to sprint to an early lead: In the next 2 years the California Fuel Cell
Partnership plans to build two hydrogen fueling stations in the state which will pump
hydrogen gas into onboard fuel tanks. As for methanol, it could take a few years before
reformers are reliable enough to mass-produce. "Until then, we've got this window to
prove the [hydrogen] technology" and to devise better ways to make it and store it,
says Sigmund Gronich, a DOE hydrogen specialist. But unless hydrogen blows away the field,
it is unlikely to conquer the passenger car arena. "As onboard fuel processing
reaches maturity in the middle of the next decade, you're probably going to see methanol
become a fuel of choice," says Sims.
Whatever version of the technology gets the checkered flag will have a long reign, says
Turner. Even if gasoline wins, it could provide a hydrogen source until fossil fuels
become scarce decades or even centuries from now. But at that point, Turner predicts,
consumers will need to switch to hydrogen, which is easier than methanol to generate from
solar power and other renewable energy sources. "Ultimately we will get there,"
says Turner. "The question is, do we generate an interim infrastructure and then 50
years from now do it all over again?"